Go to File > Preference > Settings and choose:
Workbench › Tree: Indent
Controls tree indentation in pixels.
or (in your settings.json enter this directly)
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"workbench.tree.indent": 20
you can add colorized tree indent guides to make the explorer file structure more obvious.
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{ // in settings.json
"workbench.colorCustomizations": {
"tree.indentGuidesStroke": "#00ff00"
}